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ZeDefender



Member Since: 15 Sep 2011
Location: Munich
Posts: 4731

Germany 2011 Defender 110 Puma 2.4 SW Baltic Blue
Anodic corrosion help please?
Good morning!

For various reasons, I have to use aluminium rivnuts and countersunk screws to fix my chequerplate Rolling Eyes

I would like the screws to be black for optics so normal black steel ones would achieve this - but steel and ally aren't usually very happy together Question I could also use stainless ones that would need painting... but from experience the paint usually wears off Sad

With possibilities like wet assembly with Sikaflex or ACF, can anyone give me some advice (preferably from experience)?
If I use steel, will the screws or rivnuts corrode first? (there are so many steel and ally types in published anodic tables...)

Cheers
Matt Tell someone you love them today because life is short.
But shout it at them in German because life is also terrifying and confusing...
Post #127327 28th Feb 2012 7:00am
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leeds



Member Since: 28 Dec 2009
Location: West Yorkshire
Posts: 8580

United Kingdom 
Nothing from personal experience, but it is possible to buy anodised screws/bolts in various colours. These are often used by the motorcycle crowd. I googled something like 'anodised stainless bolts' about a year ago and come up with a few potential suppliers. Price not cheap and limited to size/head/colour range unless you were buying in large quantities.

Happy googling.

Brendan
Post #127330 28th Feb 2012 7:35am
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ZeDefender



Member Since: 15 Sep 2011
Location: Munich
Posts: 4731

Germany 2011 Defender 110 Puma 2.4 SW Baltic Blue
Thanks Brendan.
I was previously looking at anodised ally screws - 2 quid a pop Shocked and I need 24 Shocked Shocked
Hadn't thought about anodised stainless Rolling Eyes
Cheers,
Matt

p.s. I still owe you money Whistle Tell someone you love them today because life is short.
But shout it at them in German because life is also terrifying and confusing...
Post #127336 28th Feb 2012 7:57am
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Green Machine



Member Since: 19 Nov 2010
Location: North Yorkshire
Posts: 1226

United Kingdom 2005 Defender 90 Td5 CSW Tonga Green
Matt,

Duralac jointing compound may be another option - it effectively isolates the fixing to prevent galvanic corrosion (primarily used in the boating world I believe). I used it when I replaced all of my door bolts with stainless, you just coat the threads, let it go tacky and then assemble. It seems to be good stuff - recommended by a few on here.

Tris. 2005 Td5 | 90 Station Wagon | Tonga Green
Post #127343 28th Feb 2012 8:24am
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Zagato
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Member Since: 08 Jan 2011
Location: Billingshurst West Sussex
Posts: 5009

United Kingdom 
Anodising kits here Wink

http://www.frost.co.uk/automotive-electrop...-kits.html

Cheaper if you are buying a lot of stuff. Some of the false anodised windscreen hinges are the same price as the kit alone. It also wears away eventually, especially the dye so to have your own kit for subsequent dippings is a good idea if you are going down this route Thumbs Up
Post #127347 28th Feb 2012 8:29am
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leeds



Member Since: 28 Dec 2009
Location: West Yorkshire
Posts: 8580

United Kingdom 
As a matter of interest what happens to the electrolytic corrosion between steel or stainless and Ali if the steel is anodised?

Or put question the other way do you need anti corrosion paste if using anodised bolts?


Brendan
Post #127352 28th Feb 2012 8:37am
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Honker



Member Since: 26 Jun 2011
Location: St Albans
Posts: 353

 2014 Defender 110 Puma 2.2 XS CSW Corris Grey
As Brendan suggests check out http://www.pro-bolt.com/ it where we've bough anodised fastners for years. Good quality and quick.

Stu
Post #127357 28th Feb 2012 8:48am
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Caterham



Member Since: 06 Nov 2008
Location: Birmingham
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England 2011 Defender 110 Puma 2.4 XS CSW Stornoway Grey
sorry going off subject a little hear but has anyone tried to install cathodic protection for there vehicle???
Post #127367 28th Feb 2012 9:16am
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davew



Member Since: 02 Jan 2012
Location: North Yorkshire
Posts: 888

England 1990 Defender 90 V8 Petrol PU Auto Rioja Red
Caterham wrote:
sorry going off subject a little hear but has anyone tried to install cathodic protection for there vehicle???


yes and no... Land Rover galvanic corrosion is generally localised and is a result of differing metals and water/damp soil acting as an electrolyte. On a boat, for example, adding a sacrificial anode is relatively simple because you are dealing with what is effectively a single structure fully immersed in an electrolyte. Having said that, having a galvanised (zinc coated) chassis will potentially offer some protection to the bodywork as the zinc is present in many areas but it won't help if you're bolting something to a panel.

For a sacrificial anode to be effective on a Land Rover you would need the node to be independently electrically connected to both the aluminium part and the steel part. This isn't really practical on a Land Rover as it's not fully immersed in water and there are so many potential paths between dissimilar metals.

The best solutions are fairly simple really. Electrically insulate the dissimilar metals from each other using one of the coatings mentioned above. Use a high zinc content primer between the two metals. Cover the joint with Dinitrol or another quality coating that will dispel moisture once it's assembled. Where a steel panel meets an aluminium panel either fit an insulating gasket between them or add a "sacrificial" aluminium shim.

Using BZP bolts is also a very good idea as the zinc in the coating provides a small amount of protection, using stainless is a bad idea as stainless is further away from aluminium then mild steel so will encourage galvanic corrosion.
Post #127390 28th Feb 2012 11:11am
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Laurie



Member Since: 22 Feb 2008
Location: Sussex, England
Posts: 2897

England 2005 Defender 90 Td5 XS CSW Bonatti Grey
Back in the days when tow sockets were made of zinc alloy instead of plastic, we all had built in sacrificial anodes. Had to replace them annually. 
Post #127395 28th Feb 2012 11:29am
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ZeDefender



Member Since: 15 Sep 2011
Location: Munich
Posts: 4731

Germany 2011 Defender 110 Puma 2.4 SW Baltic Blue
[quote="davew"]
Caterham wrote:
using stainless is a bad idea as stainless is further away from aluminium then mild steel so will encourage galvanic corrosion.


After some more research, this is my provisional conclusion.

In order of increasing destruction/reactivity when in electrical contact
1) Stainless steel
2) Steel (e.g. mild)
3) Aluminium
4) Zinc (e.g. galvanised steel)

Since I am bolting ally plate into ally rivnuts that are set into ally wings... ideally I should use ally bolts - but that would cost me 50+ quid Shocked

Stainless bolts don't corrode themselves but whatever they're bolted into often does (unless it's also stainless).

Galvanised bolts are great on their own and being close to aluminium in reactivity shouldn't harm the ally. However the zinc may corrode over time (not sure what happens then as zinc and steel straddle ally in reactivity?)

Plain old steel bolts might rust on their own anyway but since they're not far from ally in reactivity, they should only damage it slowly.

Think I may just use the steel bolts I already had Rolling Eyes and make sure the threads are all dry and full of Sikaflex. If I get corrosion problems I will see it pretty quick from the plate and switch to another material Thumbs Up Tell someone you love them today because life is short.
But shout it at them in German because life is also terrifying and confusing...
Post #127409 28th Feb 2012 1:10pm
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ZeDefender



Member Since: 15 Sep 2011
Location: Munich
Posts: 4731

Germany 2011 Defender 110 Puma 2.4 SW Baltic Blue
Zagato wrote:
Anodising kits here

I used to "blue" my rifle barrels (had a touch-up pen too) - is this the same chemical? Tell someone you love them today because life is short.
But shout it at them in German because life is also terrifying and confusing...
Post #127410 28th Feb 2012 1:13pm
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VeeTee



Member Since: 06 Mar 2011
Location: Somewhere
Posts: 1512

Netherlands 
ZeDefender wrote:

Think I may just use the steel bolts I already had Rolling Eyes and make sure the threads are all dry and full of Sikaflex. If I get corrosion problems I will see it pretty quick from the plate and switch to another material Thumbs Up


You 'd better use Duralac jointing compound instead of Sikaflex if you use SS bolts on ally.
As posted before, it really works (I have 20+ years of experience in marine applications).

Thumbs Up Cheers, Vincent
1959 Polynorm 1/4 Ton Trailer, Olive Drab Green (sold)
1970 M416 Military Trailer (Camping Trailer Conversion), Epsom Green (sold)
1975 Series III 88 V6, Light Green (sadly sold)
1996 Defender 110 CSW 300 Tdi, Epsom Green (sold)
2000 Freelander 1 TD4 3-drs, Silver (sold)
2006 Freelander 1 TD4 5-drs Facelift Automatic, Tonga Green (sold)

MySite
Post #127470 28th Feb 2012 5:00pm
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ZeDefender



Member Since: 15 Sep 2011
Location: Munich
Posts: 4731

Germany 2011 Defender 110 Puma 2.4 SW Baltic Blue
I suppose I better had Rolling Eyes
Means having to order it from UK and wait though Big Cry

... ordered... now wait...


Cheers (and yes, you told me before Laughing )
Matt Tell someone you love them today because life is short.
But shout it at them in German because life is also terrifying and confusing...
Post #127517 28th Feb 2012 7:04pm
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SteveS



Member Since: 05 Oct 2010
Location: Devon & Berkshire
Posts: 388

England 2009 Defender 110 Puma 2.4 USW Santorini Black
A reputable post market specialist dealer tried to sell me a cathodic protection system (electrical trickle) for my truck....I wrote to them basically with the same arguments that davew put forward above. Just think how would the charge get to the two sets of dissimilar metals throughout the truck - doors for example?

I politely declined their kind offer
Post #127803 29th Feb 2012 7:54pm
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